- XP and lower - C:\Documents and Settings\<Your Username>\Local Settings\Application Data\Microsoft\Outlook)
- Vista - C:\Users\<Your Username>\AppData\Local\Microsoft\Outlook
Steps for moving a Personal Folder
- Close Outlook
- Locate the .PST file
- Move it to the new location
- Open Outlook
- Use the dialog box to locate the Personal File at the new location
- Close Outlook
- Run Regedit and locate registry key HKEY_CURRENT_USER\Software\Microsoft\Office\<Version>\Outlook where <Version> is
- 10.0 for Outlook 2002
- 11.0 for Outlook 2003
- 12.0 for Outlook 2007
- Add a new a string value called ForcePSTPath and enter the new location for the offline cache (from http://support.microsoft.com/kb/883401)
- Run Mail Setup from the Control Panel
- Click on the Data Files and add a new Temporary Personal Folder (this will just be temporary as outlook won't allow you to remove an account which is associated with the default email delivery location)
- Set this Temporary Personal Folder to be the default delivery location. You may get a similar question just answer Yes
- Open and close Outlook quickly. (This sets the Temporary Personal Folder created in Step 7 to be the default delivery location)
- Back in the Mail Setup program and click on accounts and remove your Microsoft Exchange Account.
- Open and close Outlook again to clear any settings. (May not be required but doesn't hurt)
- In accounts (Step 8.) add your Microsoft Exchange account back.
- Open Outlook and it will re-create the offline cache in the location specified entered in step 2.
- Clean up by removing the Temporary Personal Folder created in step 7.
- Open Outlook to recreate the offline cache in the new location.
- Don't forget to delete the old offline cache from C: Drive.

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